Selected ATcT [1, 2] enthalpy of formation based on version 1.122e of the Thermochemical Network [3]
This version of ATcT results was generated from an expansion of version 1.122d [4] to include chemical species related to methyl acetate and methyl formate [5].| Species Name | Formula | Image | ΔfH°(0 K) | ΔfH°(298.15 K) | Uncertainty | Units | Relative Molecular Mass |
ATcT ID |
|---|---|---|---|---|---|---|---|---|
| Hydrogen fluoride | HF (aq, 10 H2O) |  | -320.87 | ± 0.16 | kJ/mol | 20.006343 ± 0.000070 | 7664-39-3*815 |
Top contributors to the provenance of ΔfH° of HF (aq, 10 H2O)
The 14 contributors listed below account for 90.1% of the provenance of ΔfH° of HF (aq, 10 H2O).Please note: The list is limited to 20 most important contributors or, if less, a number sufficient to account for 90% of the provenance. The Reference acts as a further link to the relevant references and notes for the measurement. The Measured Quantity is normaly given in the original units; in cases where we have reinterpreted the original measurement, the listed value may differ from that given by the authors. The quoted uncertainty is the a priori uncertainty used as input when constructing the initial Thermochemical Network, and corresponds either to the value proposed by the original authors or to our estimate; if an additional multiplier is given in parentheses immediately after the prior uncertainty, it corresponds to the factor by which the prior uncertainty needed to be multiplied during the ATcT analysis in order to make that particular measurement consistent with the prevailing knowledge contained in the Thermochemical Network.
Top 10 species with enthalpies of formation correlated to the ΔfH° of HF (aq, 10 H2O)
The correlation coefficient is a number from -1 to 1, with 1 representing perfectly correlated species, -1 representing perfectly anti-correlated species, and 0 representing perfectly uncorrelated species.
| Correlation Coefficent (%) | Species Name | Formula | Image | ΔfH°(0 K) | ΔfH°(298.15 K) | Uncertainty | Units | Relative Molecular Mass | ATcT ID |
|---|---|---|---|---|---|---|---|---|---|
| 99.5 | Hydrogen fluoride | HF (aq) |  | -334.49 | ± 0.16 | kJ/mol | 20.006343 ± 0.000070 | 7664-39-3*800 | |
| 99.5 | Fluoride | F- (aq) | ![[F-]](../images/504.png) | -334.49 | ± 0.16 | kJ/mol | 18.99895178 ± 0.00000050 | 16984-48-8*800 | |
| 99.4 | Hydrogen fluoride | HF (aq, 35 H2O) |  | -321.10 | ± 0.16 | kJ/mol | 20.006343 ± 0.000070 | 7664-39-3*904 | |
| 99.4 | Hydrogen fluoride | HF (aq, 37 H2O) |  | -321.11 | ± 0.16 | kJ/mol | 20.006343 ± 0.000070 | 7664-39-3*890 | |
| 99.4 | Hydrogen fluoride | HF (aq, 45 H2O) |  | -321.13 | ± 0.16 | kJ/mol | 20.006343 ± 0.000070 | 7664-39-3*906 | |
| 99.4 | Hydrogen fluoride | HF (aq, 50 H2O) |  | -321.15 | ± 0.16 | kJ/mol | 20.006343 ± 0.000070 | 7664-39-3*822 | |
| 99.4 | Hydrogen fluoride | HF (aq, 40 H2O) |  | -321.12 | ± 0.16 | kJ/mol | 20.006343 ± 0.000070 | 7664-39-3*821 | |
| 99.4 | Hydrogen fluoride | HF (aq, 55.51 H2O) |  | -321.16 | ± 0.16 | kJ/mol | 20.006343 ± 0.000070 | 7664-39-3*891 | |
| 99.4 | Hydrogen fluoride | HF (aq, 30 H2O) |  | -321.09 | ± 0.16 | kJ/mol | 20.006343 ± 0.000070 | 7664-39-3*820 | |
| 99.4 | Hydrogen fluoride | HF (aq, 55 H2O) |  | -321.16 | ± 0.16 | kJ/mol | 20.006343 ± 0.000070 | 7664-39-3*905 |
Most Influential reactions involving HF (aq, 10 H2O)
Please note: The list, which is based on a hat (projection) matrix analysis, is limited to no more than 20 largest influences.| Influence Coefficient | TN ID | Reaction | Measured Quantity | Reference |
|---|---|---|---|---|
| 0.853 | 456.2 | HF (aq, 10 H2O) → HF (aq) | ΔrH°(298.15 K) = -3.2538 ± 0.004 kcal/mol | Johnson 1973 |
| 0.146 | 456.1 | HF (aq, 10 H2O) → HF (aq) | ΔrH°(298.15 K) = -3.265 ± 0.006 (×1.61) kcal/mol | Parker 1965, NBS TN270 |
| 0.043 | 4635.1 | CF2CF2 (s) + O2 (g) + 2 H2O (cr,l) → 2 CO2 (g) + 4 HF (aq, 10 H2O) | ΔrH°(298.15 K) = -160.34 ± 0.9 kcal/mol | Scott 1955, Good 1956 |
| 0.023 | 4045.1 | CF4 (g) + 2 H2O (cr,l) → CO2 (g) + 4 HF (aq, 10 H2O) | ΔrH°(298.15 K) = -41.55 ± 1.00 kcal/mol | Scott 1955, Good 1956 |
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Note that an uncertainty of ± 0.000 kJ/mol indicates that the estimated uncertainty is < ± 0.0005 kJ/mol.
The find function is based on the complete Species Dictionary entries for the appropriate version of the ATcT TN.
The molecule images are rendered by Indigo-depict.
The XYZ renderings are based on Jmol: an open-source Java viewer for chemical structures in 3D. http://www.jmol.org/.