Selected ATcT [1, 2] enthalpy of formation based on version 1.122d of the Thermochemical Network [3]This version of ATcT results was generated from an expansion of version 1.122b [4][5] to include the enthalpies of formation of methylamine, dimethylamine and trimethylamine that were used as reference values to derive the bond dissociation energies of 20 diatomic molecules containing 3d transition metals.[6]. |
|||||||||||||||||||||||||||
| |||||||||||||||||||||||||||
Reaction Enthalpy | |||||||||||||||||||||||||||
[CH2(CHC)]- (g) → CH2(CHC) (g) | |||||||||||||||||||||||||||
→ | |||||||||||||||||||||||||||
Note: The listed uncertainity of the reaction enthalpy is computed using the full covariance matrix. | |||||||||||||||||||||||||||
|
|||||||||||||||||||||||||||
References (for your convenience, also available in RIS and BibTex format) | |||||||||||||||||||||||||||
|
|||||||||||||||||||||||||||
|
|||||||||||||||||||||||||||
Formula | |||||||||||||||||||||||||||
The aggregate state is given in parentheses following the formula, such as: g - gas-phase, cr - crystal, l - liquid, etc. | |||||||||||||||||||||||||||
|
|||||||||||||||||||||||||||
Uncertainties | |||||||||||||||||||||||||||
The listed uncertainties correspond to estimated 95% confidence limits, as customary in thermochemistry (see, for example, Ruscic [7]). Note that an uncertainty of ± 0.000 kJ/mol indicates that the estimated uncertainty is < ± 0.0005 kJ/mol. |
|||||||||||||||||||||||||||
|
|||||||||||||||||||||||||||
Website Functionality Credits | |||||||||||||||||||||||||||
The reorganization of the website was developed and implemented by David H. Bross (ANL). The find function is based on the complete Species Dictionary entries for the appropriate version of the ATcT TN. The molecule images are rendered by Indigo-depict. The XYZ renderings are based on Jmol: an open-source Java viewer for chemical structures in 3D. http://www.jmol.org/. |
|||||||||||||||||||||||||||
|
|||||||||||||||||||||||||||
Acknowledgement | |||||||||||||||||||||||||||
This work was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences under Contract No. DE-AC02-06CH11357. |